Tutorial...

The following tutorial session will take place in advance of the conference. There is a fee of €50 + VAT for the tutorial session, which permits access to both tutorials. Please book via the online registration form.

Sunday 6 September

15.30

Tutorial registration

16.00

Homoepitaxial CVD diamond growth

In this tutorial, we will discuss physical and chemical aspects of homoepitaxial CVD diamond growth, through different models commonly used. The influence of CVD process control parameters on the vapour phase properties and their consequences on the growth and film characteristics will be presented. The effect of the substrate on homoepitaxial diamond growth will also be considered.

In the second part of the tutorial, we will examine the relevant parameters governing the morphology of the growing crystals and we will introduce the difference between growth morphology and steady-state morphology. The influence of CVD growth parameters on these morphologies will be explained.

Lastly, the mechanisms responsible for the formation of structural defects within the diamond films during growth will be detailed and certain recommendations will be given in order to limit their occurrence.

Francois Silva, University Paris 13, France

17.00

Coffee break

17.30

Nano-structured diamond surfaces for bio-sensing applications
Christoph Nebel, Fraunhofer Institut für Angewandt Festkörperphysik (IAF), Freiburg, Germany

The tutorials will summarise the following topics:

I. Boron-doped diamond as electrochemical transducer

  • Optimized boron doping densities for electrochemical sensing.
  • Is n-type doping (phosphorus and nitrogen) useful for electrochemical sensing?   
  • Determination of interfacial properties like built-in potential, depletion layer.
  • Electronic interfacial properties of surfaces, terminated with hydrogen and oxygen in buffer solutions.

II. Nano-structuring of diamond using self organized and self-aligned nano-particles

  • Formation of nano-particles.
  • Plasma etching.
  • Vertically aligned diamond nano-wires: properties and dimensions.

III. Photo- and electrochemical bio-functionalization of diamond

  • Photochemical grafting: amine attachment, growth model and layer properties.
  • Electrochemical grafting: phenyl attachment, growth model and layer properties.
  • Diamond surface termination modifications by linker molecules.

IV. Diamond bio-sensor realizations for DNA and enzyme detection

  • Electrochemical sensing, using cyclic voltammetry, impedance spectroscopy, and scanning electrochemical microscopy.
  • Sensing based on IS-FET structures (DNA sensing).

V. Outlook

  • Future tends and applications of diamond for chemical and bio-chemical sensing

19.00

Tutorial ends